Gladiali, Serafino Gabriele and Fabbri, Davide (1997) Atropisomeric binaphthalene-core phosphacyclic derivatives in coordination chemistry and homogeneous catalysis. European Journal of Inorganic Chemistry, Vol. 130 (5), p. 543-554. eISSN 1099-0682. Article.
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Binaphthophospholes and binaphthophosphepines have recently been synthesized. These are the first representatives of a new class of chiral ligands that include within the same structure an endocyclic phosphorus donor, a local C2 symmetry and an axially chiral core. In this review we discuss the synthesis, chemical behaviour and first applications in asymmetric catalysis of these novel derivatives.
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