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Atropisomeric binaphthalene-core phosphacyclic derivatives in coordination chemistry and homogeneous catalysis

Gladiali, Serafino Gabriele and Fabbri, Davide (1997) Atropisomeric binaphthalene-core phosphacyclic derivatives in coordination chemistry and homogeneous catalysis. European Journal of Inorganic Chemistry, Vol. 130 (5), p. 543-554. eISSN 1099-0682. Article.

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DOI: 10.1002/cber.19971300503

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Abstract

Binaphthophospholes and binaphthophosphepines have recently been synthesized. These are the first representatives of a new class of chiral ligands that include within the same structure an endocyclic phosphorus donor, a local C2 symmetry and an axially chiral core. In this review we discuss the synthesis, chemical behaviour and first applications in asymmetric catalysis of these novel derivatives.

Item Type:Article
ID Code:9973
Status:Published
Refereed:Yes
Uncontrolled Keywords:Phosphorus heterocycles, binaphthophosphole, atropisomerism, binaphthophosphepine, hydroformylations
Subjects:Area 03 - Scienze chimiche > CHIM/04 Chimica industriale
Divisions:001 Università di Sassari > 01 Dipartimenti > Chimica
Publisher:Wiley
eISSN:1099-0682
Additional Information:Deriva dalla fusione di: Chemische Berichte. - Published online January 23, 2006.
Deposited On:15 Jul 2014 13:21

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