Solinas, Maurizio and Sechi, Barbara and Baldino, Salvatore and Chelucci, Giorgio Adolfo (2013) Synthesis and application of new iminopyridine ligands to enantioselective copper(II)-catalyzed Henry reaction. Journal of molecular catalysis A: Chemical, Vol. 378 , p. 206-212. ISSN 1381-1169. Article.
Full text not available from this repository.
Chiral iminopyridines obtained by reaction between a variety of chiral amines and pyridyl aldehydes or ketones were assessed as catalysts in the enantioselective Henry reaction between nitromethane and 2-methoxybenzaldehyde in the presence of copper(II) acetate. 1-(2-Methoxyphenyl)-2-nitroethanol was obtained in moderate yields and good enantioselectivities (up to 82% ee) under straightforward experimental conditions without the need for air or moisture exclusion. The best enantioselectivity (82% ee) was obtained by an iminopyridine based on a camphane skeleton.
I documenti depositati in UnissResearch sono protetti dalle leggi che regolano il diritto d'autore
Repository Staff Only: item control page