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In situ synchrotron radiation powder X-ray diffraction study of the 2LiNH2 + LiH + KBH4 system

Sale, Maddalena and Pistidda, Claudio and Taras, Alessandro and Napolitano, Emilio and Milanese, Chiara and Karimi, Fahim and Dornheim, Martin and Garroni, Sebastiano and Enzo, Stefano and Mulas, Gabriele Raimondo Celestino (2013) In situsynchrotron radiation powder X-ray diffraction study of the 2LiNH2 + LiH + KBH4 system. Journal of alloys and compounds, Vol. 580 (Supplement 1), S278-S281. ISSN 0925-8388. eISSN 1873-4669. Article.

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DOI: 10.1016/j.jallcom.2013.02.175


In the present work we focus on the 2LiNH2 + KBH4 + LiH system: the phase-structural transformations occurring during the desorption process on the powder mixture are described by in situ synchrotron radiation powder X-ray diffraction (SR-PXD), high-pressure differential scanning calorimetry and manometric measurements. It is observed that LiNH2 transforms into Li2NH during heating, at about 160 °C, while the reflections related to KBH4 disappeared at 380 °C. At higher temperature, the formation of Li3BN2 is detected, together with an evident increase of the background, ascribable to the presence of a further phase in the molten state. Patterns at room temperature, after cooling down the sample, confirm the presence of Li3BN2 and KH as reported in the theoretical study. For the as prepared mixture it is possible to achieve the theoretical hydrogen gravimetric capacity of 7.4 wt%.

Item Type:Article
ID Code:9860
Uncontrolled Keywords:Hydrogen storage in solid state, complex hydrides, in situ synchrotron radiation powder x-ray diffraction (SR-PXD), Lithium amide, Lithium hydride
Subjects:Area 03 - Scienze chimiche > CHIM/02 Chimica fisica
Divisions:002 Altri enti e centri di ricerca del Nord Sardegna > INSTM-Consorzio Interuniversitario Nazionale per la Scienza e la Tecnologia dei Materiali, Unità di ricerca di Sassari
001 Università di Sassari > 01-a Nuovi Dipartimenti dal 2012 > Chimica e Farmacia
Deposited On:09 Jun 2014 13:34

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