Baldino, Salvatore (2009) Sintesi ed applicazione in catalisi asimmetrica di derivati piridinici chiarli e non: fenantroline amino-piridine, amino-chinoline e fosfino-piridine. Doctoral Thesis.
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This thesis mainly concerns two important areas of Organic Chemistry: synthesis
and catalysis. In particular our aim was to synthesize new pyridine-based ligands
and to prove their ability in catalytic asymmetric reactions. Moreover we explored
alternative approaches for the synthesis of molecules of interest in different fields
We can briefly summarize our results as follows:
1. The achievement of a new procedure to obtain optically active 1-
substituted-1-(pyridin-2-yl)methylamines by diastereoselective reduction of
2. The synthesis of new pincer CNN ligands based on the benzo[h]quinoline
framework and catalytic applications of their Ru- and Os-complexes.
3. The development of alternative approaches to the synthesis of 1,10-
phenanthrolines and to compounds that are key-intermediates in the
synthesis of the 1,10-phenanthroline core.
4. The synthesis of a new pyridine-based N-P ligand derived from optically
active camphor and some preliminary results about its activity in catalytic
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