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Heterobimetallic rollover derivatives

Petretto, Giacomo Luigi and Rourke, Jonathan P. and Maidich, Luca and Stoccoro, Sergio and Cinellu, Maria Agostina and Minghetti, Giovanni and Clarkson, Guy J. and Zucca, Antonio (2012) Heterobimetallic rollover derivatives. Organometallics, Vol. 31 (8), p. 2971-2977. eISSN 1520-6041. Article.

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DOI: 10.1021/om200660a


Heterobimetallic complexes with metal centers connected by a small delocalized ligand constitute an interesting class of compounds. Here we report that starting from the mononuclear platinum(II) rollover complexes [Pt(bipy-H)(L)Cl] (bipy-H = 2,2′-bipyridine C(3′)-N cyclometalated, L= DMSO, PPh3) a second rollover cyclometalation may produce a series of Pt(II)/Pd(II) heterobimetallic complexes where the two metals are linked by the planar, highly delocalized, doubly deprotonated 2,2′-bipyridine.

Item Type:Article
ID Code:8795
Uncontrolled Keywords:Heterobimetallic complexes, mononuclear platinum(II) rollover complexes
Subjects:Area 03 - Scienze chimiche > CHIM/03 Chimica generale e inorganica
Divisions:001 Università di Sassari > 01-a Nuovi Dipartimenti dal 2012 > Chimica e Farmacia
Publisher:American Chemical Society
Deposited On:14 Mar 2013 13:46

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