Luo, Shu-Ping and Mejía, Esteban and Friedrich, Aleksej and Pazidis, Alexandra and Junge, Henrik and Surkus, Annette-Enrica and Jackstell, Ralf and Denurra, Stefania and Gladiali, Serafino Gabriele and Lochbrunner, Stefan and Beller, Matthias (2013) Photocatalytic water reduction with copper-based photosensitizers: a noble-metal-free system. Angewandte Chemie. International Edition, Vol. 52 (1), p. 419-423. eISSN 1521-3773. Article.
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Of noble descent: A fully noble-metal-free system for the photocatalytic reduction of water at room temperature has been developed. This system consists of CuI complexes as photosensitizers and [Fe3(CO)12] as the water reduction catalyst. The novel Cu-based photosensitizers are relatively inexpensive, readily available from commercial sources and stable to ambient conditions, thus making them an attractive alternative to the widely used noble-metal based systems.
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