Castaldi, Paola and Gibson, Susan E. and Rudd, Matthew and White, Andrew J.P. (2005) A New approach to enantiopure C3-symmetric molecules. Chemistry: a European Journal, Vol. 12 (1), p. 138-148. eISSN 1521-3765. Article.
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Chiral base chemistry has been used to create three chiral centres in one pot on a C3-symmetric substrate. The potential of this new approach to C3-symmetric molecules is exemplified by the creation of an enantiopure C3v-symmetric triol, triphosphane and tripyridine. A ruthenium complex of the last compound has been studied by X-ray crystallography.
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