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A New approach to enantiopure C3-symmetric molecules

Castaldi, Paola and Gibson, Susan E. and Rudd, Matthew and White, Andrew J.P. (2005) A New approach to enantiopure C3-symmetric molecules. Chemistry: a European Journal, Vol. 12 (1), p. 138-148. eISSN 1521-3765. Article.

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DOI: 10.1002/chem.200501031


Chiral base chemistry has been used to create three chiral centres in one pot on a C3-symmetric substrate. The potential of this new approach to C3-symmetric molecules is exemplified by the creation of an enantiopure C3v-symmetric triol, triphosphane and tripyridine. A ruthenium complex of the last compound has been studied by X-ray crystallography.

Item Type:Article
ID Code:7361
Uncontrolled Keywords:Asymmetric synthesis, chiral bases, chromium, ruthenium, structure elucidation
Subjects:Area 07 - Scienze agrarie e veterinarie > AGR/13 Chimica agraria
Divisions:001 Università di Sassari > 01 Dipartimenti > Scienze ambientali agrarie e biotecnologie agro-alimentari
Publisher:Blackwell / Wiley
Deposited On:12 Apr 2012 08:55

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