Synthesis of an enantioenriched C2-symmetric molecule by a chiral-base-mediated kinetic resolution of an (Arene)tricarbonylchromium(0) complex

Synthesis of an enantioenriched C₂-symmetric molecule by a chiral-base-mediated kinetic resolution of an (Arene)tricarbonylchromium(0) complex

Castaldi, Paola and Gibson, Susan E. and White, Andrew J.P. (2006) Synthesis of an enantioenriched C₂-symmetric molecule by a chiral-base-mediated kinetic resolution of an (Arene)tricarbonylchromium(0) complex. European Journal of Organic Chemistry, Vol. 2006 (8), p. 1867-1875. eISSN 1099-0690. Article.

Full text not available from this repository.

DOI: 10.1002/ejoc.200600018

Abstract

Trimethylsilyl substituents have been used to control the conformational preferences of a 1,2-disubstituted (arene)tricarbonylchromium(0) complex. The kinetic resolution of the mono-methyl derivative (±)-11 using a chiral base/iodome-thane quench sequence led to the synthesis of the enantioenriched C₂-symmetric bis-ether (+)-13.

Item Type:	Article
ID Code:	7360
Status:	Published
Refereed:	Yes
Uncontrolled Keywords:	(Arene)tricarbonylchromium(0) complex, asymmetric synthesis, C₂ symmetry, chiral base, conformational control, kinetic resolution
Subjects:	Area 07 - Scienze agrarie e veterinarie > AGR/13 Chimica agraria
Divisions:	001 Università di Sassari > 01 Dipartimenti > Scienze ambientali agrarie e biotecnologie agro-alimentari
Publisher:	Wiley
eISSN:	1099-0690
Deposited On:	11 Apr 2012 13:34

I documenti depositati in UnissResearch sono protetti dalle leggi che regolano il diritto d'autore

Repository Staff Only: item control page