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Synthesis of an enantioenriched C2-symmetric molecule by a chiral-base-mediated kinetic resolution of an (Arene)tricarbonylchromium(0) complex

Castaldi, Paola and Gibson, Susan E. and White, Andrew J.P. (2006) Synthesis of an enantioenriched C2-symmetric molecule by a chiral-base-mediated kinetic resolution of an (Arene)tricarbonylchromium(0) complex. European Journal of Organic Chemistry, Vol. 2006 (8), p. 1867-1875. eISSN 1099-0690. Article.

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DOI: 10.1002/ejoc.200600018

Abstract

Trimethylsilyl substituents have been used to control the conformational preferences of a 1,2-disubstituted (arene)tricarbonylchromium(0) complex. The kinetic resolution of the mono-methyl derivative (±)-11 using a chiral base/iodome-thane quench sequence led to the synthesis of the enantioenriched C2-symmetric bis-ether (+)-13.

Item Type:Article
ID Code:7360
Status:Published
Refereed:Yes
Uncontrolled Keywords:(Arene)tricarbonylchromium(0) complex, asymmetric synthesis, C2 symmetry, chiral base, conformational control, kinetic resolution
Subjects:Area 07 - Scienze agrarie e veterinarie > AGR/13 Chimica agraria
Divisions:001 Università di Sassari > 01 Dipartimenti > Scienze ambientali agrarie e biotecnologie agro-alimentari
Publisher:Wiley
eISSN:1099-0690
Deposited On:11 Apr 2012 13:34

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