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Introduction of multiple elements of chirality around an aromatic core and an approach to enantiomerically pure C3-symmetric ligands

Castaldi, Paola and Gibson, Susan E. and Rudd, Matthew and White, Andrew J.P. (2005) Introduction of multiple elements of chirality around an aromatic core and an approach to enantiomerically pure C3-symmetric ligands. Angewandte Chemie, Vol. 117 (22), p. 3498-3501. eISSN 1521-3757. Article.

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DOI: 10.1002/ange.200500020

Abstract

Mithilfe chiraler Basen gelang es, mehrere Chiralitätselemente in einen (Aren)tricarbonylchrom(0)-Komplex einzuführen. In einem einzigen Schritt wurden bei der Synthese eines nichtracemischen chiralen C3-symmetrischen Triphosphins und eines nichtracemischen chiralen C3-symmetrischen Tripyridins (siehe Schema) vier stereogene Zentren erzeugt.

Item Type:Article
ID Code:7359
Status:Published
Refereed:Yes
Uncontrolled Keywords:Asymmetrische Synthesen, Chirale Basen, Phosphine, Symmetrie, Tripyridine
Subjects:Area 07 - Scienze agrarie e veterinarie > AGR/13 Chimica agraria
Divisions:001 Università di Sassari > 01 Dipartimenti > Scienze ambientali agrarie e biotecnologie agro-alimentari
Publisher:Wiley
eISSN:1521-3757
Deposited On:11 Apr 2012 14:14

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