Azzena, Ugo Gavino and Pittalis, Mario and Dettori, Giovanna and Madeddu, Simona and Azara, Emanuela (2006) Reducing properties of 1,2-diaryl-1,2-disodiumethanes. Tetrahedron Letters, Vol. 47 (7), p. 1055-1058. ISSN 0040-4039. Article.
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1,2-Diphenyl- and 1-phenyl-2-(2-pyridyl)-1,2-disodiumethane efficiently dehalogenate vic-dibromoderivatives, affording the corresponding alkenes. The reaction proceeds rapidly, under mild conditions and is tolerant of a variety of functional groups (alcohol, carboxylic acid, ester and amide). This procedure was successfully extended to similar vic-disubstituted compounds.
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