Manca, Paola and Pilo, Maria Itria and Sanna, Gavino and Zucca, Antonio and Bergamini, Giacomo and Ceroni, Paola (2011) Ru2+ complexes comprising terpyridine ligands appended with terthiophene chromophores: energy transfer and energy reservoir effect. Chemical Communications, Vol. 47 (12), p. 3413-3415. eISSN 1364-548X. Article.
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Two Ru2+ complexes containing terpyridine ligands appended with terthiophene units connected by a methyleneoxy or an alkynyl bridge show very different luminescent behaviours: the former is non-luminescent at 298 K owing to a photoinduced energy transfer process to the terthiophene moiety, while the latter exhibits an extraordinary long excited state lifetime because of an energy reservoir effect.
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