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BINEPINES: chiral binaphthalene-core monophosphepine ligands for multipurpose asymmetric catalysis

Gladiali, Serafino Gabriele and Alberico, Elisabetta and Junge, Kathrin and Beller, Matthias (2011) BINEPINES: chiral binaphthalene-core monophosphepine ligands for multipurpose asymmetric catalysis. Chemical Society Reviews, Vol. 40 (7), p. 3744-3763. ISSN 0306-0012. eISSN 1460-4744. Article.

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DOI: 10.1039/c0cs00164c


The atropisomeric structure of 4,5-dihydro-3H-dinaphtho[2,1-c;1',2'-e]phosphepine is the common axially chiral scaffold of a library of monophosphine ligands nicknamed BINEPINES that have shown a quite remarkable stereoselection efficiency in a broad variety of enantioselective reactions involving the formation of new C–H or C–C or C–X bonds. In this critical review the properties and scope of this type of chiral ligands are illustrated (70 references).

Item Type:Article
ID Code:6258
Uncontrolled Keywords:BINEPINES, chiral monophosphines, organocatalysis
Subjects:Area 03 - Scienze chimiche > CHIM/04 Chimica industriale
Divisions:001 Università di Sassari > 01 Dipartimenti > Chimica
002 Altri enti e centri di ricerca del Nord Sardegna > CNR-Consiglio Nazionale delle Ricerche > Istituto di chimica biomolecolare, Sassari
Publisher:Royal Society of Chemistry
Copyright Holders:© The Royal Society of Chemistry 2011
Deposited On:14 Jul 2011 10:04

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