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Hafnia sol-gel films synthesized from HfCl4: changes of structure and properties with the firing temperature

Kidchob, Tongjit and Malfatti, Luca and Serra, Filomena and Falcaro, Paolo and Enzo, Stefano and Innocenzi, Plinio (2007) Hafnia sol-gel films synthesized from HfCl4: changes of structure and properties with the firing temperature. Journal of Sol-Gel Science and Technology, Vol. 42 (1), p. 89-93. eISSN 1573-4846. Article.

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DOI: 10.1007/s10971-006-1511-9


Thin sol-gel hafnia films have been synthesised from HfCl4, the synthesis has revealed to be a simple route to fabrication of hafnia films with high transparency in the UV-visible range. The films have been fired at different temperatures in air up to 1000°C and have been characterized by X-ray diffraction and Fourier transform infrared spectroscopy. Infrared absorption spectra of hafnia films have allowed to follow the formation of monoclinic crystalline phases together with XRD. Formation of monoclinic hafnia crystallites has been observed upon calcination at temperatures higher than 600°C, as shown by infrared spectroscopy and XRD. The optical transmission and the refractive index as a function of the temperature of firing have been characterized by UV-Visible spectroscopy and spectroscopic ellipsometry. The hafnia films, after firing at 600°C, had a refractive index of 1.92 with a thickness of around 70 nm.

Item Type:Article
ID Code:613
Uncontrolled Keywords:Hafnia, films, infrared spectroscopy, XRD
Subjects:Area 03 - Scienze chimiche > CHIM/02 Chimica fisica
Area 09 - Ingegneria industriale e dell'informazione > ING-IND/22 Scienza e tecnologia dei materiali
Divisions:001 Università di Sassari > 01 Dipartimenti > Chimica
001 Università di Sassari > 01 Dipartimenti > Architettura e pianificazione
Publisher:Springer Netherlands
Copyright Holders:© Springer Science + Business Media, LLC 2007
Deposited On:18 Aug 2009 10:02

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