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Concise diastereospecific pyrrolo[1,2-a][1,4]benzodiazepinone synthesis

Mucedda, Mauro and Muroni, Daniele and Saba, Antonio and Manassero, Carlo (2007) Concise diastereospecific pyrrolo[1,2-a][1,4]benzodiazepinone synthesis. Tetrahedron, Vol. 63 (49), p. 12232-12238. ISSN 0040-4020. Article.

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DOI: 10.1016/j.tet.2007.09.062


A concise synthesis of the novel pyrrolo[1,2-a]benzodiazepine system, by using the metallo carbenoid/spiro-[6,5]-ammonium ylide/Stevens[1,2]-shift with ring-expansion approach, was reported. The overall cascade process resulted stereospecific.

Item Type:Article
ID Code:5995
Uncontrolled Keywords:Benzodiazepines, diazo compounds, cascade process, Stevens[ 1,2]-shift
Subjects:Area 03 - Scienze chimiche > CHIM/06 Chimica organica
Divisions:001 Università di Sassari > 01 Dipartimenti > Chimica
Publisher:Pergamon / Elsevier
Deposited On:22 Apr 2011 12:08

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