Convergent synthesis of mosloflavone, negletein and baicalein from crysin

Righi, Giuliana and Antonioletti, Roberto and Proietti Silvestri, Ilaria and D'Antona, Nicola and Lambusta, Daniela and Bovicelli, Paolo (2010) Convergent synthesis of mosloflavone, negletein and baicalein from crysin. Tetrahedron, Vol. 66 (6), p. 1294-1298. ISSN 0040-4020. Article.

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DOI: 10.1016/j.tet.2009.12.021

Abstract

An expeditious synthesis of three polyoxygenated flavones: mosloflavone, negletein and baicalein, starting from crysin, an easily available flavone, by a bromination/methoxylation procedure is reported. The convergent synthesis exploits a base induced Wesley–Moser type rearrangement.

Item Type:	Article
ID Code:	5693
Status:	Published
Refereed:	Yes
Uncontrolled Keywords:	Mosloflavone, negletein, baicalein, flavone
Subjects:	Area 05 - Scienze biologiche > BIO/10 Biochimica
Divisions:	002 Altri enti e centri di ricerca del Nord Sardegna > CNR-Consiglio Nazionale delle Ricerche > Istituto di chimica biomolecolare, Sassari
Publisher:	Pergamon / Elsevier
ISSN:	0040-4020
Copyright Holders:	© 2009 Elsevier
Deposited On:	07 Mar 2011 18:23

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