De Sio, Vincenzo and Acocella, Maria Rosaria and Villano, Rosaria and Scettri, Arrigo (2010) New chiral imino- and amino-sulfoxides as activators of allyl trichlorosilane in the asymmetric allylation of aldehydes. Tetrahedron: Asymmetry, Vol. 21 (11-12), p. 1432-1435. eISSN 1362-511X. Article.
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Chiral 2-methylsulfinyl benzaldehyde proved to be a valuable starting material for a convenient approach towards a variety of imino- and amino-sulfoxides. The catalytic properties of these new ligands, as potential activators of allyl trichlorosilane, have been exploited in new catalytic procedures for the synthesis of enantioenriched homoallylic alcohols.
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