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New chiral imino- and amino-sulfoxides as activators of allyl trichlorosilane in the asymmetric allylation of aldehydes

De Sio, Vincenzo and Acocella, Maria Rosaria and Villano, Rosaria and Scettri, Arrigo (2010) New chiral imino- and amino-sulfoxides as activators of allyl trichlorosilane in the asymmetric allylation of aldehydes. Tetrahedron: Asymmetry, Vol. 21 (11-12), p. 1432-1435. eISSN 1362-511X. Article.

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DOI: 10.1016/j.tetasy.2010.04.015

Abstract

Chiral 2-methylsulfinyl benzaldehyde proved to be a valuable starting material for a convenient approach towards a variety of imino- and amino-sulfoxides. The catalytic properties of these new ligands, as potential activators of allyl trichlorosilane, have been exploited in new catalytic procedures for the synthesis of enantioenriched homoallylic alcohols.

Item Type:Article
ID Code:5585
Status:Published
Refereed:Yes
Uncontrolled Keywords:Asymmetric synthesis, allylation, catalysis
Subjects:Area 03 - Scienze chimiche > CHIM/06 Chimica organica
Divisions:002 Altri enti e centri di ricerca del Nord Sardegna > CNR-Consiglio Nazionale delle Ricerche > Istituto di chimica biomolecolare, Sassari
Publisher:Pergamon / Elsevier
eISSN:1362-511X
Copyright Holders:© 2010 Elsevier
Additional Information:Special issue: Henri Kagan: an 80th birthday celebration, part 2., edited by Jean-Claude Fiaud and John M. Brown.
Deposited On:11 Mar 2011 11:52

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