Lubinu, Maria Caterina and De Luca, Lidia Vera Giovanna and Giacomelli, Giampaolo and Porcheddu, Andrea (2011) Microwave-promoted selective mono-N-alkylation of anilines with tertiary amines by heterogeneous catalysis. Chemistry: a European Journal, Vol. 17 (1), p. 82-85. eISSN 1521-3765. Article.
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A palladium-catalyzed N-alkylation of anilines with tertiary amines that occurs under heterogeneous transfer-hydrogenation conditions has been developed. This protocol of transamination, which uses a relatively cheap and easily recyclable heterogeneous catalyst, can be efficiently applied to different substrates and is suitable for large-scale preparations.
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