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Microwave-promoted selective mono-N-alkylation of anilines with tertiary amines by heterogeneous catalysis

Lubinu, Maria Caterina and De Luca, Lidia Vera Giovanna and Giacomelli, Giampaolo and Porcheddu, Andrea (2011) Microwave-promoted selective mono-N-alkylation of anilines with tertiary amines by heterogeneous catalysis. Chemistry: a European Journal, Vol. 17 (1), p. 82-85. eISSN 1521-3765. Article.

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DOI: 10.1002/chem.201002704

Abstract

A palladium-catalyzed N-alkylation of anilines with tertiary amines that occurs under heterogeneous transfer-hydrogenation conditions has been developed. This protocol of transamination, which uses a relatively cheap and easily recyclable heterogeneous catalyst, can be efficiently applied to different substrates and is suitable for large-scale preparations.

Item Type:Article
ID Code:5408
Status:Published
Refereed:Yes
Uncontrolled Keywords:Alkylation, amines, anilines, heterogeneous catalysis, microwave chemistry
Subjects:Area 03 - Scienze chimiche > CHIM/06 Chimica organica
Divisions:001 Università di Sassari > 01 Dipartimenti > Chimica
Publisher:Blackwell / Wiley
eISSN:1521-3765
Deposited On:31 Jan 2011 13:50

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