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Synthesis and molecular structure of [Pd{CH2CH2C(O)Me}(HL)][BAr‘4] (HL = 6-Me-2,2‘-bipyridine, Ar‘ = 3,5-(CF3)2C6H3), an intermediate relevant to ethene/CO copolymerization

Stoccoro, Sergio and Minghetti, Giovanni and Cinellu, Maria Agostina and Zucca, Antonio and Manassero, Mario (2001) Synthesis and molecular structure of [Pd{CH2CH2C(O)Me}(HL)][BAr‘4] (HL = 6-Me-2,2‘-bipyridine, Ar‘ = 3,5-(CF3)2C6H3), an intermediate relevant to ethene/CO copolymerization. Organometallics, Vol. 20 (19), p. 4111-4113. eISSN 1520-6041. Article.

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DOI: 10.1021/om010278f

Abstract

In the ethene/CO copolymerization catalyzed by palladium derivatives, species arising from ethene insertion into the palladium-acyl bond have been shown to play a key role. We report here the synthesis, spectroscopic characterization, and X-ray structure of the complex [Pd{CH2CH2C(O)Me}(HL)][BAr'4] (HL ) 6-Me- 2,2'-bipyridine, Ar' ) 3,5-(CF3)2C6H3), 4, the first one having an ancillary N,N ligand to be characterized in the solid state.

Item Type:Article
ID Code:5350
Status:Published
Refereed:Yes
Uncontrolled Keywords:Ethene/CO copolymerization, palladium derivatives, [Pd{CH2CH2C(O)Me}(HL)][BAr'4] (HL ) 6-Me- 2,2'-bipyridine, Ar' ) 3,5-(CF3)2C6H3)
Subjects:Area 03 - Scienze chimiche > CHIM/03 Chimica generale e inorganica
Divisions:001 Università di Sassari > 01 Dipartimenti > Chimica
Publisher:American Chemical Society
eISSN:1520-6041
Deposited On:31 Jan 2011 08:56

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