Zucca, Antonio and Doppiu, Angelino and Cinellu, Maria Agostina and Stoccoro, Sergio and Minghetti, Giovanni and Manassero, Mario (2002) Multiple C−H bond activation: threefold-deprotonated 6-phenyl-2,2‘-bipyridine as a bridging ligand in dinuclear platinum(II) derivatives. Organometallics, Vol. 21 (5), p. 783-785. eISSN 1520-6041. Article.
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Unusual platinum(II) trimetalated derivatives have been synthesized and characterized by reaction of cis-[Pt(R)2(DMSO)2] (R = Me, Ph) and 6-phenyl-2,2‘-bipyridine. The behavior of the substituted 2,2‘-bipyridine as a threefold-deprotonated ligand is unprecedented.
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