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Multiple C−H bond activation: threefold-deprotonated 6-phenyl-2,2‘-bipyridine as a bridging ligand in dinuclear platinum(II) derivatives

Zucca, Antonio and Doppiu, Angelino and Cinellu, Maria Agostina and Stoccoro, Sergio and Minghetti, Giovanni and Manassero, Mario (2002) Multiple C−H bond activation: threefold-deprotonated 6-phenyl-2,2‘-bipyridine as a bridging ligand in dinuclear platinum(II) derivatives. Organometallics, Vol. 21 (5), p. 783-785. eISSN 1520-6041. Article.

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DOI: 10.1021/om010913h

Abstract

Unusual platinum(II) trimetalated derivatives have been synthesized and characterized by reaction of cis-[Pt(R)2(DMSO)2] (R = Me, Ph) and 6-phenyl-2,2‘-bipyridine. The behavior of the substituted 2,2‘-bipyridine as a threefold-deprotonated ligand is unprecedented.

Item Type:Article
ID Code:4929
Status:Published
Refereed:Yes
Uncontrolled Keywords:C-H bond, platinum(II) derivatives, bipyridines
Subjects:Area 03 - Scienze chimiche > CHIM/03 Chimica generale e inorganica
Divisions:001 Università di Sassari > 01 Dipartimenti > Chimica
Publisher:American Chemical Society
eISSN:1520-6041
Deposited On:22 Nov 2010 19:03

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