titoli, abstracts, parole chiave >>>
Cyclometallated derivatives of platinum(II) derived from 1,4-benzodiazepin-2-ones: crystal and molecular structure of Pt(L)(HL)Cl(HL=7-chloro-1,3-dihydro-1-methyl-5-phenyl-2H-1,4-benzodiazepin-2-one, DIAZEPAM), a molecule containing a neutral and a deprotonated 1,4-benzodiazepin-2-one

Stoccoro, Sergio and Cinellu, Maria Agostina and Zucca, Antonio and Minghetti, Giovanni and Demartin, Francesco (1994) Cyclometallated derivatives of platinum(II) derived from 1,4-benzodiazepin-2-ones: crystal and molecular structure of Pt(L)(HL)Cl(HL=7-chloro-1,3-dihydro-1-methyl-5-phenyl-2H-1,4-benzodiazepin-2-one, DIAZEPAM), a molecule containing a neutral and a deprotonated 1,4-benzodiazepin-2-one. Inorganica Chimica Acta, Vol. 215 (1-2), p. 17-26. ISSN 0020-1693. Article.

Full text not available from this repository.

DOI: 10.1016/0020-1693(93)03699-B

Abstract

The complexes [Pt(L)Cl]2 (1), Pt(L)(HL)Cl (2), (two conformers, 2a and 2b), Pt(L)(Ph3P)Cl (3), Pt(L)(3,5-Me2t-py)Cl (4) and Pt(L)(CO)Cl (5) (HL=7-chloro-1,3-dihydro-1-methyl-5-phenyl-2H-1,4-benzodiazepin-2-one, DIAZEPAM) have been prepared and characterized by IR, MS and 1H, 13C, 31p and two-dimensional correlation NMR spectra. Complexes 1-5 contain a deprotonated DIAZEPAM coordinated to the metal through the N(4) atom and the ortho-carbon of the 5-phenyl substituent. In complex 2, as shown by a sing]e crystal X-ray structure determination, carried out on conformer 2a, in addition to the cyclometallated system, a neutral molecule of DIAZEPAM is coordinated through the N(4) atom. The crystals of compound 2a, C32H25Cl3N4O2Pt, are monoclinic, space group P21/n with a = 13.601(3), b = 15.951(5), c = 13.837(3) Å, β = 96.38(2)°, Z = 4. The structure was refined to R = 0.021 and Rw = 0.032 on the basis of 4922 unique reflections with I>3σ(I). The platinum atom is in a square planar geometry with the carbon atom trans to the chloride ligand: Pt---C=1.983(3), Pt---Cl=2.402(1), Pt---N=2.031(3) and 2.009(3) Å.

Item Type:Article
ID Code:4917
Status:Published
Refereed:Yes
Uncontrolled Keywords:Crystal structures, platinum complexes, cyclometallated ligand complexes, hydrido complexes
Subjects:Area 03 - Scienze chimiche > CHIM/03 Chimica generale e inorganica
Divisions:001 Università di Sassari > 01 Dipartimenti > Chimica
Publisher:Elsevier Science
ISSN:0020-1693
Deposited On:22 Nov 2010 15:48

I documenti depositati in UnissResearch sono protetti dalle leggi che regolano il diritto d'autore

Repository Staff Only: item control page