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Cyclometallated derivatives of palladium(II) and platinum(II) derived from 6-t-butyl-2,2′-bipyridine

Stoccoro, Sergio and Chelucci, Giorgio Adolfo and Cinellu, Maria Agostina and Zucca, Antonio and Minghetti, Giovanni (1993) Cyclometallated derivatives of palladium(II) and platinum(II) derived from 6-t-butyl-2,2′-bipyridine. Journal of Organometallic Chemistry, Vol. 450 (1-2), p. C15-C16. ISSN 0022-328X. Article.

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DOI: 10.1016/0022-328X(93)80172-8


The synthesis of the cyclometallated derivatives [PdLCl] and [PtLCl](HL = 6-t-butyl-2,2′-bipyridine) is reported. The deprotonated bipyridine is terdentate through the two nitrogen atoms and a carbon atom of the t-butyl substituent. The new complexes were characterized by 1H and 13C NMR and FAB-MS spectra.

Item Type:Article
ID Code:4912
Uncontrolled Keywords:Palladium(II), platinum(II), cyclometallated derivatives
Subjects:Area 03 - Scienze chimiche > CHIM/06 Chimica organica
Area 03 - Scienze chimiche > CHIM/03 Chimica generale e inorganica
Divisions:001 Università di Sassari > 01 Dipartimenti > Chimica
Publisher:Elsevier Science
Deposited On:22 Nov 2010 15:19

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