Ghezzo, E. and Traldi, Pietro and Minghetti, Giovanni and Cinellu, Maria Agostina and Bandini, Anna Laura and Banditelli, Guido and Zecca, Luigi (1990) Fast-Atom bombardment mass spectrometry and collisional spectroscopy in the structural characterization of underivatized 1,4-benzodiazepines. Rapid Communications in Mass Spectrometry, Vol. 4 (9), p. 314-317. eISSN 1097-0231. Article.
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Fast-atom bombardment (FAB) mass spectrometry linked with collision spectroscopy has been employed for the structural characterization of eight underivatized 1,4-benzodiazepines. Both positive- and negative-ion FAB led, in all cases examined, to the production of abundant molecular species. Collision experiments performed on such ions gave rise to the identification of diagnostic fragment ions, that could be related to the original structure.
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