Cinellu, Maria Agostina and Ganadu, Maria Luisa Margherita and Minghetti, Giovanni and Cariati, Francesco and Demartin, Francesco and Manassero, Mario (1988) Adducts and cyclometallated derivatives of palladium(II) with some 1,4-benzodiazepin-2-ones: crystal and molecular structure of trans-dichlorobis[7-chloro-1-(cyclopropylmethyl)-1,3-dihydro-5-phenyl-2H-1,4-benzodiazepin-2-one] palladium(II). Inorganica Chimica Acta, Vol. 143 (2), p. 197-207. ISSN 0020-1693. Article.
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The adducts trans-L2PdCl2 (1, L = Diazepam = 7- chloro-1,3-dihydro-1-methyl-5-phenyl-2H-1,4-benzodiazepin -2-one; 5, L = Prazepam = 7-chloro-1-(cyclopropylmethyl)- 1,3-dihydro-5-phenyl-2H-1,4-benzodiazepin-2-one) were prepared by reaction of PdCl2 or (PhCN)2PdCl2 with Diazepam and Prazepam, respectively.
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