Minghetti, Giovanni and Ganadu, Maria Luisa Margherita and Foddai, Candida and Cinellu, Maria Agostina and Cariati, Francesco and Demartin, Francesco and Manassero, Mario (1984) Synthesis and characterization of gold(III) complexes of 1,4-benzodiazepin-2-ones: crystal structure of trichloro-[7-chloro-1-(cyclopropylmethyl)-1,3-dihydro-5-phenyl-2H-1,4-benzodiazepin-2-one]gold(III). Inorganica Chimica Acta, Vol. 86 (2), p. 93-100. ISSN 0020-1693. Article.
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The reaction of gold(III) chloride with several 1,4-benzodiazepin-2-ones, L, gives 1:1 adducts, (L)AuCl3*, which were characterized by IR, Raman and 1H NMR spectroscopy. In the title compound the coordination of the ligand, ascertained through a X-ray structure determination, was shown to occur through the 4-nitrogen atom.
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