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Reaction of gold(III) oxo complexes with alkenes: synthesis of unprecedented gold alkene complexes, [Au(N,N)(alkene)][PF6]: crystal structure of [Au(bipyip)(η2-CH2 CHPh)][PF6] (bipyip = 6-isopropyl-2,2 -bipyridine)

Cinellu, Maria Agostina and Minghetti, Giovanni and Stoccoro, Sergio and Zucca, Antonio and Manassero, Mario (2004) Reaction of gold(III) oxo complexes with alkenes: synthesis of unprecedented gold alkene complexes, [Au(N,N)(alkene)][PF6]: crystal structure of [Au(bipyip)(η2-CH2 CHPh)][PF6] (bipyip = 6-isopropyl-2,2 -bipyridine). Chemical Communications, Vol. 14 , p. 1618-1619. eISSN 1364-548X. Article.

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DOI: 10.1039/b404890c

Abstract

Gold alkene complexes [Au(bipyR)(η 2-alkene)][PF6] (bipyR = 6-alkyl-2,2 -bipyridine) have been obtained by reaction of gold(III) oxo complexes [Au2(bipyR)2(µ-O)2][PF6]2 with alkenes. The crystal structure of the styrene adduct [Au(bipyip)(η 2-CH2 CHPh)][PF6] (bipyip = 6-isopropyl-2,2 -bipyridine) has been solved by X-ray analysis.

Item Type:Article
ID Code:4022
Status:Published
Refereed:Yes
Uncontrolled Keywords:Alkene ligands, gold, oxidation, oxo ligands
Subjects:Area 03 - Scienze chimiche > CHIM/03 Chimica generale e inorganica
Divisions:001 Università di Sassari > 01 Dipartimenti > Chimica
Publisher:Royal Society of Chemistry
eISSN:1364-548X
Deposited On:16 Jun 2010 13:01

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