Chelucci, Giorgio Adolfo and Muroni, Daniele and Pinna, Gérard Aimé and Saba, Antonio and Vignola, Davide (2003) Chiral 2-(2-phenylthiophenyl)-5,6,7,8-tetrahydroquinolines: new N-S ligands for asymmetric catalysis Palladium-catalyzed allylic alkylation and copper-catalyzed cyclopropanation reactions. Journal of Molecular Catalysis A. Chemical, Vol. 191 (1), p. 1-8. ISSN 1381-1169. Article.
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Diastereomeric pure 2-(2-phenylthiophenyl)-5,6,7,8-tetrahydroquinolines were prepared and assessed in the enantioselective palladium-catalyzed allylic substitution of 1,3-diphenylprop-2-enyl acetate with dimethyl malonate and in the copper-catalyzed cyclopropanation of styrene with ethyldiazoacetate. Enantioselectivity up to 63% was obtained.
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