Fritzsche, Siegfried and Wolfsberg, Max and Haberlandt, Reinhold and Demontis, Pierfranco and Suffritti, Giuseppe Baldovino and Tilocca, Antonio (1998) About the influence of lattice vibrations on the diffusion of methane in a cation-free LTA zeolite. Chemical Physics Letters, Vol. 296 (3-4), p. 253-258. ISSN 0009-2614. Article.
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The influence of lattice vibrations on the diffusion of methane in a cation-free zeolite of structure Type LTA is examined. It is shown that contrary to earlier published results the self-diffusion coefficients obtained with flexible and with rigid lattices are practically the same. This finding is true over a wide range of temperatures and for different interaction parameters. The reason why earlier papers did not state this independence of D on the lattice vibrations is explained.
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