Minghetti, Giovanni and Pilo, Maria Itria and Sanna, Gavino and Seeber, Renato and Stoccoro, Sergio and Laschi, Franco (1993) Electrochemical and spectroelectrochemical study of cyclometallated platinum derivatives with nitrogen ligands: electrogeneration of monomeric reduced platinum species. Journal of Organometallic Chemistry, Vol. 452 (1-2), p. 257-261. ISSN 0022-328X. Article.
Full text not available from this repository.
The cathodic reduction of the complexes [LPtCl] and [LPtL′] (BF4) [HL = 6-(1-methylbenzyl)-2,2′-bipyridine and L′= triphenylphosphine, pyridine, or acetonitrile] has been studied in acetonitrile and dichloromethane solvents. The main goal has been that of defining the nature and reactivity of the corresponding relatively stable one-electron reduced forms. In particular, X-band EPR spectrometry has allowed us to get information about the character (metal- or ligand-based) of the unpaired extra electron of the reduced species.
I documenti depositati in UnissResearch sono protetti dalle leggi che regolano il diritto d'autore
Repository Staff Only: item control page