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Sintesi, reattività, chiralità in complessi di Pt(II)

Sini, Alessandro (2010) Sintesi, reattività, chiralità in complessi di Pt(II). Doctoral Thesis.

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Abstract

My PhD thesis concerns basically the synthesis and reactivity of organometallic platinum(II) complexes with pyridine and bipyridine ligands. These complexes are very interesting due to their applications in many fields: catalysis, biology and farmacology, photophysic and photochemistry. Chirality of several complexes with 2-R-pyridines, S-(-)-nicotine and 1,2-bis(2-pyridil)benzene has been carefully taken into account. Concerning bipyridine complexes, reactivity with carbon monoxide and phosphines (triphenilphosphine and tricycloesilphosphine) has been investigated, leading to substitution and insertion products.
Finally an interesting complex of platinum(II) with bulky phosphines has been synthesised. The reaction of this compound with molecular hydrogen results in a heterolytic splitting of H2 molecule.

Item Type:Doctoral Thesis
ID Code:3470
Publisher:Universita' degli studi di Sassari
Uncontrolled Keywords:Platino(II), complessi organometallici, chiralità, piridina, bipiridina inserzioni
Subjects:Area 03 - Scienze chimiche > CHIM/03 Chimica generale e inorganica
Divisions:001 Università di Sassari > 01 Dipartimenti > Chimica
Cicli, scuole e corsi:Ciclo 22 > Scuole > Scienze e tecnologie chimiche > Scienze chimiche
Deposited On:26 Mar 2010 13:28

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