Mariani, Alberto and Bidali, Simone and Fiori, Stefano and Sangermano, Marco and Malucelli, Giulio and Bongiovanni, Roberta and Priola, Aldo (2004) UV-ignited frontal polymerization of an epoxy resin. Journal of Polymer Science. Part A: Polymer Chemistry, Vol. 42 (9), p. 2066-2072. eISSN 1099-0518. Article.
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By combining frontal polymerization and radical-induced cationic polymerization, it was possible to cure thick samples of an epoxy monomer bleached by UV light. The effect of the relative amounts of cationic photoinitiator and radical initiator was thoroughly investigated and was related to the front's velocity and its maximum temperature. The materials obtained were characterized by quantitative conversion also in the deeper layers, not reached by UV light.
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