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New vistas in frontal polymerization

Mariani, Alberto and Bidali, Simone and Fiori, Stefano and Malucelli, Giulio and Ricco, Laura (2004) New vistas in frontal polymerization. Macromolecular Symposia, Vol. 218 (1), p. 1-10. eISSN 1521-3900. Article.

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DOI: 10.1002/masy.200451401


Frontal Polymerization is a technique for the synthesis of polymers that, by exploiting the heat liberated by the self-same reaction, generates a hot front that can sustain and propagate itself from one end of the reactor to the other converting monomer into polymer. After the activation and following formation of the front, it is not necessary to provide any other form of energy in order to carry out polymerization. In this article we will summarize some of the recent results we have obtained in the application of Frontal Polymerization to the preparation of polyurethanes, unsaturated polyester resins, and polyacrylates.

Item Type:Article
ID Code:2524
Uncontrolled Keywords:Atom transfer radical polymerization (ATRP), frontal polymerization, polyacrylates, polyurethanes, unsaturated polyester resins
Subjects:Area 03 - Scienze chimiche > CHIM/04 Chimica industriale
Divisions:001 Università di Sassari > 01 Dipartimenti > Chimica
Additional Information:Paper presented at: Current topics in polymer science and technology: [16th meeting of the Macromolecular Italian Association (AIM)], Pisa, Italy, September 22-25, 2003.
Deposited On:18 Aug 2009 10:08

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