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Reactions of gold(III) oxo complexes with cyclic alkenes

Cinellu, Maria Agostina and Minghetti, Giovanni and Cocco, Fabio and Stoccoro, Sergio and Zucca, Antonio and Manassero, Mario (2005) Reactions of gold(III) oxo complexes with cyclic alkenes. Angewandte Chemie. International Edition, Vol. 44 (42), p. 6892-6895. eISSN 1521-3773. Article.

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DOI: 10.1002/anie.200501754


An auraoxetane, obtained from the reaction of norbornene with a gold(III) oxo complex, has been isolated and fully characterized (see structure). Action of the olefin leads to elimination of the epoxide from the auraoxetane.

Item Type:Article
ID Code:2434
Uncontrolled Keywords:Alkene ligands, gold, oxidation, oxo ligands
Subjects:Area 03 - Scienze chimiche > CHIM/03 Chimica generale e inorganica
Divisions:001 Università di Sassari > 01 Dipartimenti > Chimica
Deposited On:18 Aug 2009 10:07

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