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Copper(II) chloride complexes of 2-(4'-Methyl-2'-pyridyl)-benzoxazole, their sulphur and nitrogen analogues and 2-(4'-Methyl-2' {or8'} -quinolyl)benzoxazoles

Massacesi, Marcella and Ponticelli, Gustavo and Devoto, Gerolamo and Micera, Giovanni and Piu, Paola Costantina (1984) Copper(II) chloride complexes of 2-(4'-Methyl-2'-pyridyl)-benzoxazole, their sulphur and nitrogen analogues and 2-(4'-Methyl-2' {or8'} -quinolyl)benzoxazoles. Transition Metal Chemistry, Vol. 9 (9), p. 362-366. eISSN 1572-901X. Article.

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DOI: 10.1007/BF00618560

Abstract

Copper(II) complexes CuLCl2, where L=2-(4-methyl-2-pyridyl)benzimidazole(mpbi); 2-(4-methyl-2-pyridyl)benzothiazole(mpbt); 2-(4-methyl-2-pyridyl)benzoxazole (mpbo); 2-(4-methyl-2-quinolyl)benzoxazole (mqbo); 2-(4-methyl8-quinolyl)benzoxazole (mqbo), and Cu(mpbi)2Cl2(H2O) have been synthesized and characterized by conductivity and magnetic measurements as well as by i.r., electronic and e.s.r. spectra. The ligands are bidentate donors through the pyridine and isoxazole nitrogen atoms. The CuLCl2 complexes exhibit spectral properties consistent with CuN2Cl2 chromophores differing in the degree of tetrahedral distortion, which is found to parallel the steric hindrance near the donor sites. Cu(mpbi)2 Cl2(H2O) is five-coordinate.

Item Type:Article
ID Code:1457
Status:Published
Refereed:Yes
Uncontrolled Keywords:Copper(II), chloride complexes, benzoxazoles
Subjects:Area 03 - Scienze chimiche > CHIM/03 Chimica generale e inorganica
Area 03 - Scienze chimiche > CHIM/01 Chimica analitica
Divisions:001 Università di Sassari > 01 Dipartimenti > Chimica
Publisher:Springer Netherlands
eISSN:1572-901X
Deposited On:18 Aug 2009 10:05

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