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Co-ordination ability of Cu2+ ion toward the nucleobase-amino acid willardiine

Chruscinska, Elzebieta and Garribba, Eugenio and Micera, Giovanni and Panzanelli, Angelo and Biagioli, Marco (1998) Co-ordination ability of Cu2+ ion toward the nucleobase-amino acid willardiine. Talanta, Vol. 47 (2), p. 343-348. ISSN 0039-9140. Article.

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DOI: 10.1016/S0039-9140(98)00130-1

Abstract

The complex formation between CuII and DL-willardiine [1-(2-amino-2-carboxyethyl)uracil], an analog of phenylalanine containing the uracil residue, was investigated by potentiometric and spectral studies. The results indicate that the primary metal binding site of the ligand is the α-amino-carboxylate chelating set. The uracil moiety, however, can coordinate the metal ion in basic solution giving rise to intermolecular bridging.

Item Type:Article
ID Code:1439
Status:Published
Refereed:Yes
Uncontrolled Keywords:Willardiine, [1-(2-Amino-2-carboxyethyl)uracil], uracylalanine, Cu(II) complexes
Subjects:Area 03 - Scienze chimiche > CHIM/03 Chimica generale e inorganica
Area 03 - Scienze chimiche > CHIM/01 Chimica analitica
Divisions:001 Università di Sassari > 01 Dipartimenti > Chimica
Publisher:Elsevier
ISSN:0039-9140
Deposited On:18 Aug 2009 10:05

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