Palombi, Luigi and Bocchino, Carmen and Caruso, Tonino and Villano, Rosaria and Scettri, Arrigo (2008) Electro- and acid-catalysis in tetrafluoroborate-based ionic liquid: new alternative routes for the oxidation of sulfides with UHP. Tetrahedron Letters, Vol. 49 (39), p. 5611-5613. ISSN 0040-4039. Article.
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By means of anodic activation, BF4-based ionic liquid was found to play the triple role of electrolysis/reaction medium, supporting electrolyte and pre-catalyst versus the oxidation of sulfides with UHP. Galvanostatic electrolysis in the presence of substrate and UHP molecules allowed the fast, efficient and selective achievement of sulfoxides. Comparable results have been attained by acid catalysis based on R-CSA.
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