Cathodic C-H electro-activation in ionic liquid: an improved electrochemical method for the conjugate addition of 1,3-dicarbonyl compounds

Palombi, Laura and Bocchino, Carmen and Caruso, Tonino and Villano, Rosaria and Scettri, Arrigo (2008) Cathodic C-H electro-activation in ionic liquid: an improved electrochemical method for the conjugate addition of 1,3-dicarbonyl compounds. Catalysis Communications, Vol. 10 (3), p. 321-324. ISSN 1566-7367. Article.

Full text not available from this repository.

DOI: 10.1016/j.catcom.2008.09.017

Abstract

The constant current electrolysis of 1,3-dicarbonyl compounds in 1-ethyl-3-methylimidazolium ethylsulfate (EMIMEtSO4) ionic liquid provided the direct deprotonation of the methylene active functionality to the cathode: the corresponding enolates efficiently underwent to the one-pot Michael addition with activated olefins.

Item Type:	Article
ID Code:	1378
Status:	Published
Refereed:	Yes
Uncontrolled Keywords:	C–H electro-activation, electrolysis, 1,3-dicarbonyl compounds, ionic liquid
Subjects:	Area 03 - Scienze chimiche > CHIM/03 Chimica generale e inorganica
Divisions:	002 Altri enti e centri di ricerca del Nord Sardegna > CNR-Consiglio Nazionale delle Ricerche > Istituto di chimica biomolecolare, Sassari
Publisher:	Elsevier
ISSN:	1566-7367
Additional Information:	Pubblicato online il 30 settembre 2008.
Deposited On:	18 Aug 2009 10:05

I documenti depositati in UnissResearch sono protetti dalle leggi che regolano il diritto d'autore

Repository Staff Only: item control page