Brusatin, Giovanna and Della Giustina, Gioia and Guglielmi, Massimo and Innocenzi, Plinio (2006) Photocurable glycidoxypropyltrimethoxysilane based sol-gel hybrid materials. Progress in Solid State Chemistry, Vol. 34 (2-4), p. 223-229. ISSN 0079-6786. Article.
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Hybrid sol-gel materials are promising candidates for electro/optical applications, combining the most important glass-like and polymer-like properties. Hybrid patternable materials produced by photopolymerisation processes have been mainly developed on 3-methacrloxypropyltrimethoxysilane based systems in which the polymerisable organic function is the C‗C bond of the methacrylic group. A new photosensitive hybrid material is described here, based on 3-glycidoxypropyltrimethoxysilane (GPTMS) and on the cationic photopolymerisation of the epoxide groups, which lead to the formation of a PEO organic interpenetrating network.
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