Chelucci, Giorgio Adolfo and Cabras, Maria Antonietta (1996) Enantioselective palladium catalyzed allylic substitution with sulfur-containing pyridine ligands. Tetrahedron: Asymmetry, Vol. 7 (4), p. 965-966. ISSN 0957-4166. Article.
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Diastereomerically pure (5R,7R,8S)- and (5R,7R,8R)-5,6,7,8-tetrahydro-6,6-dimethyl-2-phenyl-8-phenyltio-5,7-methanoquinoline were prepared and assessed in the enantioselective palladium catalyzed allylic substitution of 1,3-diphenylprop-2-enyl acetate with dimethylmalonate. Enantioselectivities up to 83 % were obtained.
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