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Enantioselective palladium catalyzed allylic substitution with sulfur-containing pyridine ligands

Chelucci, Giorgio Adolfo and Cabras, Maria Antonietta (1996) Enantioselective palladium catalyzed allylic substitution with sulfur-containing pyridine ligands. Tetrahedron: Asymmetry, Vol. 7 (4), p. 965-966. ISSN 0957-4166. Article.

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DOI: 10.1016/0957-4166(96)00092-4

Abstract

Diastereomerically pure (5R,7R,8S)- and (5R,7R,8R)-5,6,7,8-tetrahydro-6,6-dimethyl-2-phenyl-8-phenyltio-5,7-methanoquinoline were prepared and assessed in the enantioselective palladium catalyzed allylic substitution of 1,3-diphenylprop-2-enyl acetate with dimethylmalonate. Enantioselectivities up to 83 % were obtained.

Item Type:Article
ID Code:1187
Status:Published
Refereed:Yes
Uncontrolled Keywords:Enantioselective palladium, allylic substitution, palladium complex, pyridine ligands
Subjects:Area 03 - Scienze chimiche > CHIM/06 Chimica organica
Area 03 - Scienze chimiche > CHIM/03 Chimica generale e inorganica
Divisions:001 Università di Sassari > 01 Dipartimenti > Chimica
Publisher:Pergamon / Elsevier
ISSN:0957-4166
Copyright Holders:© 1996 Elsevier Science
Deposited On:18 Aug 2009 10:04

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