Chelucci, Giorgio Adolfo and Cabras, Maria Antonietta and Saba, Antonio and Sechi, Alessandra (1996) Synthesis and resolution of 1,1-bi-8-methylisoquinoline: formation of an optically active complex with high chiral recognition. Tetrahedron: Asymmetry, Vol. 7 (4), p. 1027-1032. ISSN 0957-4166. Article.
Full text not available from this repository.
The synthesis and resolution of 1,1-bi-8-methylisoquinoline (±)-5 is reported. An optically active palladium complex with high chiral recognition was formed during the complexation between a chiral palladium complex and the two enantiomers of (±)-5. The free energy barrier ΔG≠ for interconversion of enantiomers was estimated to be 97,2 KJ/mol at 40 °C.
I documenti depositati in UnissResearch sono protetti dalle leggi che regolano il diritto d'autore
Repository Staff Only: item control page