Synthesis and resolution of 1,1-bi-8-methylisoquinoline: formation of an optically active complex with high chiral recognition

Chelucci, Giorgio Adolfo and Cabras, Maria Antonietta and Saba, Antonio and Sechi, Alessandra (1996) Synthesis and resolution of 1,1-bi-8-methylisoquinoline: formation of an optically active complex with high chiral recognition. Tetrahedron: Asymmetry, Vol. 7 (4), p. 1027-1032. ISSN 0957-4166. Article.

Full text not available from this repository.

DOI: 10.1016/0957-4166(96)00107-3

Abstract

The synthesis and resolution of 1,1-bi-8-methylisoquinoline (±)-5 is reported. An optically active palladium complex with high chiral recognition was formed during the complexation between a chiral palladium complex and the two enantiomers of (±)-5. The free energy barrier ΔG≠ for interconversion of enantiomers was estimated to be 97,2 KJ/mol at 40 °C.

Item Type:	Article
ID Code:	1179
Status:	Published
Refereed:	Yes
Uncontrolled Keywords:	1,1-bi-8-methylisoquinoline (±)-5, palladium complex, high chiral recognition
Subjects:	Area 03 - Scienze chimiche > CHIM/06 Chimica organica Area 03 - Scienze chimiche > CHIM/03 Chimica generale e inorganica
Divisions:	001 Università di Sassari > 01 Dipartimenti > Chimica
Publisher:	Pergamon / Elsevier
ISSN:	0957-4166
Copyright Holders:	© 1996 Elsevier Science
Deposited On:	18 Aug 2009 10:04

I documenti depositati in UnissResearch sono protetti dalle leggi che regolano il diritto d'autore

Repository Staff Only: item control page