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Ruthenium and osmium complexes containing 2-(aminomethyl)pyridine (Ampy)-based ligands in catalysis

Chelucci, Giorgio Adolfo and Baldino, Salvatore and Baratta, Walter (2015) Ruthenium and osmium complexes containing 2-(aminomethyl)pyridine (Ampy)-based ligands in catalysis. Coordination chemistry reviews, Vol. 300 , p. 29-85. ISSN 0010-8545. Article.

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DOI: 10.1016/j.ccr.2015.04.007

Abstract

This account focuses on the application in catalysis of ruthenium and osmium complexes containing 2-(aminomethyl)pyridine (Ampy)-based ligands. The combination of these aminoalkylpyridine ligands with appropriate phosphines affords ruthenium and osmium systems displaying unprecedented high catalytic activity and productivity in a variety of organic transformations such as hydrogenation by hydrogen transfer and dihydrogen, dehydrogenation, racemization, and alkylation.

Item Type:Article
ID Code:11018
Status:Published
Refereed:Yes
Uncontrolled Keywords:Ruthenium complexes, oosmium complexes, aminoalkylpyridines, transfer hydrogenation, hydrogenation, catalysis, asymmetric catalysis
Subjects:Area 07 - Scienze agrarie e veterinarie > AGR/13 Chimica agraria
Divisions:001 Università di Sassari > 01-a Nuovi Dipartimenti dal 2012 > Agraria
Publisher:Elsevier
ISSN:0010-8545
Deposited On:10 Jul 2015 18:43

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