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Synthesis and application in asymmetric catalysis of camphor-based pyridine ligands

Chelucci, Giorgio Adolfo (2006) Synthesis and application in asymmetric catalysis of camphor-based pyridine ligands. Chemical Society Reviews, Vol. 35 (12), p. 1230-1243. ISSN 0306-0012. eISSN 1460-4744. Article.

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DOI: 10.1039/B604793A

Abstract

This tutorial review deals with the synthesis and application in asymmetric catalysis of camphor-based pyridine ligands. These ligands can be roughly divided into two groups: those in which the camphor is annulated in the 2,3-positions to the β-face of the pyridine ring and those in which the pyridine is contained as a pendant on the C2 or C3 of the camphor framework. Camphor-based pyridine ligands can also contain other donor centers located on the pyridine ring or camphor skeleton. Some of these ligands have provided interesting enantioselectivities in several asymmetric reactions, such as SN2′ reactions, allylic oxidations, carbonyl additions with organozinc reagents and hydrogenations. This review contains a lot of chemistry on ligand synthesis and readers will find it of value and also perhaps an inspiration for the development of more active and improved versions.

Item Type:Article
ID Code:10760
Status:Published
Refereed:Yes
Uncontrolled Keywords:Asymmetric catalysis of camphor-based pyridine ligands, synthesis, application
Subjects:Area 03 - Scienze chimiche > CHIM/06 Chimica organica
Divisions:001 Università di Sassari > 01 Dipartimenti > Chimica
Publisher:Royal Society of Chemistry
ISSN:0306-0012
eISSN:1460-4744
Deposited On:05 Feb 2015 10:54

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