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Chiral 2,2'-Bipyridines, 1,10-Phenanthrolines, and 2,2':6',2''-Terpyridines: syntheses and applications in asymmetric homogeneous catalysis

Chelucci, Giorgio Adolfo and Thummel, Randolph P. (2002) Chiral 2,2'-Bipyridines, 1,10-Phenanthrolines, and 2,2':6',2''-Terpyridines: syntheses and applications in asymmetric homogeneous catalysis. Chemical reviews, Vol. 102 (9), p. 3129-3170. ISSN 0009-2665. eISSN 1520-6890. Article.

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DOI: 10.1021/cr0101914

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Abstract

Although chiral phosphines have enjoyed a longtime popularity in the design of enantioselective catalytic systems, there has been a recent renaissance in the use of nitrogen ligands for this same purpose.1 This renaissance partly arises from several distinct advantages presented by nitrogen-containing ligands. First, they can often be employed in catalytic processes where the use of phosphines may be incompatible with the reaction conditions. Second, many nitrogen ligands are now available in enantiomerically pure form. Third, ligands that bind through nitrogen are known to coordinate with a wide variety of metal ions, and considerable progress has been made in understanding the role which these ligands play in affecting catalytic processes.

Item Type:Article
ID Code:10740
Status:Published
Refereed:Yes
Uncontrolled Keywords:Chiral phosphines, nitrogen ligands, pyridine ring, enantioselective catalytic systems
Subjects:Area 03 - Scienze chimiche > CHIM/06 Chimica organica
Divisions:001 Università di Sassari > 01-a Nuovi Dipartimenti dal 2012 > Agraria
Publisher:American Chemical Society
ISSN:0009-2665
eISSN:1520-6890
Deposited On:03 Feb 2015 09:30

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