Chelucci, Giorgio Adolfo and Pinna, Gérard Aimé and Pinna, Giansalvo (2014) Regioselective hydrodebromination of polybrominated indoles. European Journal of Organic Chemistry, Vol. 2014 (18), p. 3802-3807. eISSN 1099-0690. Article.
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The mixture of sodium borohydride and N,N,N′,N′-tetramethylethylenediamine in combination with a palladium catalyst is a mild and efficient system for the regioselective hydrodebromination of polybrominated indoles with both N-donating and N-withdrawing substituents [N-methyl- and N-(methoxycarbonyl)indoles, respectively].
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