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Regioselective hydrodebromination of polybrominated indoles

Chelucci, Giorgio Adolfo and Pinna, Gérard Aimé and Pinna, Giansalvo (2014) Regioselective hydrodebromination of polybrominated indoles. European Journal of Organic Chemistry, Vol. 2014 (18), p. 3802-3807. eISSN 1099-0690. Article.

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DOI: 10.1002/ejoc.201400032

Abstract

The mixture of sodium borohydride and N,N,N′,N′-tetramethylethylenediamine in combination with a palladium catalyst is a mild and efficient system for the regioselective hydrodebromination of polybrominated indoles with both N-donating and N-withdrawing substituents [N-methyl- and N-(methoxycarbonyl)indoles, respectively].

Item Type:Article
ID Code:10350
Status:Published
Refereed:Yes
Uncontrolled Keywords:Synthetic methods, nitrogen heterocycles, bromine, reduction, palladium
Subjects:Area 03 - Scienze chimiche > CHIM/06 Chimica organica
Area 03 - Scienze chimiche > CHIM/08 Chimica farmaceutica
Divisions:001 Università di Sassari > 01-a Nuovi Dipartimenti dal 2012 > Agraria
001 Università di Sassari > 01-a Nuovi Dipartimenti dal 2012 > Chimica e Farmacia
Publisher:Wiley
eISSN:1099-0690
Deposited On:21 Nov 2014 10:16

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