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A Mixed valent heterometallic CuII/NaI coordination polymer with sodium–phenyl bonds

Datta, Amitabha and Das, Kuheli and Massera, Chiara and Clegg, Jack K. and Sinha, Chittaranjan and Huang, Jui-Hsien and Garribba, Eugenio (2014) A Mixed valent heterometallic CuII/NaI coordination polymer with sodium–phenyl bonds. Dalton Transactions, Vol. 43 (14), p. 5558-5563. ISSN 1477-9226. Article.

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DOI: 10.1039/C4DT00189C


A mixed valent heterometallic CuII/NaI coordination polymer (1) is generated by the reaction of a Schiff base ligand, (6,6′-(1E,1′E)-(2-hydroxypropane-1,3-diyl)bis(azan-1-yl-1-ylidene)bis(methan-1-yl-1-ylidene)bis(2-methoxyphenol)) with copper(II) acetate and sodium perchlorate. In addition to the presence of alcohol oxygen—sodium coordination bonds, the single crystal X-ray structure reveals that the 1D coordination polymer is stabilised by the formation of phenyl—sodium η2-bonds, face-to-face π–π contacts and Cu–π interactions.

Item Type:Article
ID Code:10247
Uncontrolled Keywords:Coordination bonds, schiff-base ligands, single crystal x-ray structures
Subjects:Area 03 - Scienze chimiche > CHIM/03 Chimica generale e inorganica
Divisions:001 Università di Sassari > 02 Centri > Centro di eccellenza interdisc. sviluppo ricerca biotecnologica e studio biodiversità della Sardegna e dell'area mediterranea
001 Università di Sassari > 01-a Nuovi Dipartimenti dal 2012 > Chimica e Farmacia
Publisher:Royal Society of Chemistry
Deposited On:31 Oct 2014 08:26

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