Carroccia, Laura and Degennaro, Leonardo and Romanazzi, Giuseppe and Cuocci, Corrado and Pisano, Luisa and Luisi, Renzo (2014) Straightforward access to 4-membered sulfurated heterocycles: introducing a strategy for the single and double functionalization of thietane 1-oxide. Organic & Biomolecular Chemistry, Vol. 12 (14), p. 2180-2184. ISSN 1477-0520. Article.
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A strategy for the stereoselective functionalization of thietane 1-oxide has been developed. Mono (C2 substituted) and doubly (C2, C4 disubstituted) functionalized thietanes have been obtained from the readily available thietane 1-oxide by using the corresponding organometallic intermediates that reacted with electrophiles leaving intact the 4-membered ring.
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