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Straightforward access to 4-membered sulfurated heterocycles: introducing a strategy for the single and double functionalization of thietane 1-oxide

Carroccia, Laura and Degennaro, Leonardo and Romanazzi, Giuseppe and Cuocci, Corrado and Pisano, Luisa and Luisi, Renzo (2014) Straightforward access to 4-membered sulfurated heterocycles: introducing a strategy for the single and double functionalization of thietane 1-oxide. Organic & Biomolecular Chemistry, Vol. 12 (14), p. 2180-2184. ISSN 1477-0520. Article.

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DOI: 10.1039/c4ob00173g

Abstract

A strategy for the stereoselective functionalization of thietane 1-oxide has been developed. Mono (C2 substituted) and doubly (C2, C4 disubstituted) functionalized thietanes have been obtained from the readily available thietane 1-oxide by using the corresponding organometallic intermediates that reacted with electrophiles leaving intact the 4-membered ring.

Item Type:Article
ID Code:10246
Status:Published
Refereed:Yes
Uncontrolled Keywords:Sulfurated heterocycles, thietanes, organometallic intermediates, electrophiles
Subjects:Area 03 - Scienze chimiche > CHIM/06 Chimica organica
Divisions:001 Università di Sassari > 01-a Nuovi Dipartimenti dal 2012 > Chimica e Farmacia
Publisher:Royal Society of Chemistry
ISSN:1477-0520
Deposited On:31 Oct 2014 08:23

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