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Stereospecific hydrodehalogenation of alkenyl bromides: a new approach to the synthesis of (E)-alkenes

Chelucci, Giorgio Adolfo (2014) Stereospecific hydrodehalogenation of alkenyl bromides: a new approach to the synthesis of (E)-alkenes. Chemical Communications, Vol. 50 (31), p. 4069-4072. eISSN 1364-548X. Article.

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DOI: 10.1039/C4CC00345D

Abstract

The pair NaBH4—TMEDA and catalytic PdCl2PPh3)2 in THF at room temperature is a mild and efficient system for the hydrodebromination of alkenyl bromides, providing a facile reduction procedure that allows completing the process advantageously, leading from aldehydes to (E)-alkenes.

Item Type:Article
ID Code:10239
Status:Published
Refereed:Yes
Uncontrolled Keywords:Alkenyl bromides, hydrodehalogenation, synthesis of alkenes
Subjects:Area 03 - Scienze chimiche > CHIM/06 Chimica organica
Divisions:001 Università di Sassari > 01-a Nuovi Dipartimenti dal 2012 > Agraria
Publisher:Royal Society of Chemistry
eISSN:1364-548X
Deposited On:29 Oct 2014 15:09

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